Applications of electrolysis, Electroplating, Purification of metals & Extraction of aluminum from bauxite

Electrolysis is used to separate electrolyte components by the electric current, Electrolytic cells are used in Electroplating, Purification of metals, Extraction of aluminum from bauxite, Electroplating is the process of the formation of a thin layer in a certain metal on the surface of another metal to give it a nice shiny view or to protect it from corrosion.

Electroplating

Electroplating is used to protect the metal from corrosion and rusting, It gives metals a lustrous appearance, It gives metals more expensive value, such as plating some cars parts which manufactured from steel by chromium layer to take a beautiful shape and also to protect it from corrosion, Healthy tools as tap water, mixers are electroplated by chromium or gold.

Electroplating of a jug by a layer of silver
  1. Clean a surface of jug completely.
  2. Dip the jug and the rod of Ag into electrolyte solution that contains silver ions.
  3. Connect the jug with the −ve electrode of the battery (cathode) and a rod of silver metal to the +ve electrode (anode).
  4. Switch on the circuit.

When the electric current passes through the circuit: Oxidation process takes place at the anode where silver (Ag+) ions dissolve in the solution, AgºAg+ + e, Reduction process takes place at the cathode, Ag+ + eAgº, so, silver atoms precipitate on the surface of the jug, According to Faraday’s first law, the amount of silver deposited on the jug is directly proportional to the quantity of electric current passed through the solution.

The purification of copper by electrolysis

Copper of purity 99% includes some impurities like Fe, Zn, Ag & Au, These impurities decrease the conductivity of copper for the electricity, Impure copper metal is connected to the +ve electrode (anode) of the battery, while a wire of fine pure copper sheets is connected to the -ve electrode (cathode).

Both of the anode and cathode are dipped into a solution of copper sulphate CuSO4, when the electric current passes, the ions will move towards the electrodes opposite to their charges: CuSO4 Cu2+ + SO4−2

Oxidation process takes place at the anode: Cuº Cu2+ + 2 e

Iron and zinc impurities dissolve in the solution, while silver and gold impurities failed down the anode.

Znº Zn2+ + 2 e

FeºFe2+ + 2 e

Reduction process takes at the cathode to precipitate pure copper atoms at the cathode.

Cu2+ + 2 eCuº

Copper with purity less than 99.95 % is not used in the manufacturing of electric wires because the impurities decrease the ability of copper for electrical conductance and also its quality.

Some of the impurities in anode as Zn and Fe dissolve in the solution forming Zn2+, Fe2+ due to they have high oxidation potential, but they do not precipitated on cathode during purification of copper because they have low reduction potential.

Au and Ag impurities do not dissolve in the solution because they have low oxidation potential, so they sink below the anode and then removed as metals from the bottom, In this process 99.95 % pure copper can be obtained.

Extraction of Aluminum

Aluminum is extracted from (Al2O3) by electrolysis in the presence of cryolite (Na3AlF6) and fluorspar (calcium fluoride CaF2), Cryolite (Na3AlF6) is used to dissolve and ionize aluminum oxide.

Bauxite (Al2O3) is used to extract Aluminium electrically, Cryolite (Na3AlF6) containing a little of fluorspar (CaF2) act as solvents for bauxite and decrease the mixture melting point from 2045° C to 950° C.

Recently cryolite is replaced by a mixture of fluoride salts of (sodium, aluminum and calcium) to reduce the melting point and the density of the molten aluminum which facilitates the separation of molten aluminum at the bottom of the electrolytic cell.

Extraction of Aluminum

Extraction of Aluminum

Structure of the cell

The anode consists of rods of carbon (graphite), The cathode is the container, which is made of iron lined with a layer of carbon (graphite), The body of the container is connected to the negative electrode of the electric source and acts as a cathode.

Carbon rods are connected to the positive electrode of the electric source and act as an anode, when electric current passes between the cell electrodes which dipped in molten bauxite (Al2O3) which is dissolved in cryolite (Na3AlF6) containing a little of fluorspar (CaF2), an oxidation-reduction occurs:

3 O2−3/2 O2 + 6 e, oxidation at the anode (+)

2 Al3+ + 6 e  2 Alº , reduction at the cathode (−)

The total reaction: 2 Al3+ + 3 O2−2 Alº + 3/2 O2

Aluminum is withdrawn from the cell through a special opening, The evolved oxygen reacts with the carbon electrodes forming carbon mono and carbon dioxides, It is necessary to change graphite electrodes in bauxite cell because they are corroded by reacting with evolved oxygen.

3/2 O2 + 2 C CO + CO2

Faraday’s laws of electrolysis (Faraday’s first laws & Faraday’s Second law), Quantity of electricity and equivalent weight

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