Substitution reactions, Chemical activity series, types of simple & double substitution reactions

Substitution reactions occur when there is an active element replaces (substitutes) another less active element in another compound. Metals are arranged according to the degree of their chemical activity in a series, which is known as the “chemical activity series“.

Substitution reactions

Chemical activity series (C.A.S.) is the arrangement of metals in a descending order according to the degree of their chemical activity. The arrangement of metallic elements in the chemical activity series to compare between elements concerning the degree of chemical activity, where the more active element replaces the less active one. Substitution reactions are classified into two types:

  1. Simple substitution reactions.
  2. Double substitution reactions.

Simple substitution reactions

Simple substitution reactions are chemical reactions in which one of the elements substitutes another less active element in a solution of one of its compounds.

Simple substitution reactions

Simple substitution reactions

Types of simple substitution reactions

  • A metal substitutes the hydrogen of water.
  • A metal substitutes the hydrogen of diluted acid.
  • A metal substitutes another metal in its salt solution.
A metal substitutes the hydrogen of water

Metals that precede hydrogen in C.A.S. substitute hydrogen of water forming metal hydroxide and hydrogen gas evolves.

Substitution of sodium to a hydrogen of water

Procedures:
  1. Put a small piece of sodium by using tongs in a glass of water.
  2. Touch the glass of water carefully after ending the reaction.

Be careful when performing this reaction as this will lead to explosion and also burning. So, you must use a small piece of sodium (which is preserved under the surface of kerosene).

Observations:
  1. Sodium burns with a pop sound (explosion).
  2. The glass of water becomes warm.
Conclusion:

Sodium substitutes the hydrogen of water giving sodium hydroxide and hydrogen gas evolves which burns with a pop sound and the reaction is accompanied by releasing of heat.

2Na + 2H2O2NaOH + H2 ↑ + Heat

A metal substitutes the hydrogen of diluted acid

Metals that precede hydrogen in C.A.S. substitute hydrogen of diluted acid-forming salt of the acid and hydrogen gas evolves.

Active metal + An acid Salt of the acid + Hydrogen gas

Metals that come after hydrogen in the chemical activity series cannot substitute hydrogen of diluted acid (except under certain conditions).

Substitution of some metals to hydrogen of diluted acid
Procedures:
  1. Put equal amounts of dil. hydrochloric acid in three test tubes.
  2. Add 3 sheets of equal sizes as follows:
  • A sheet of zinc in the first tube.
  • A sheet of aluminium in the second tube.
  • A sheet of copper in the third tube.
Observations:

Gas bubbles evolve immediately on adding the sheet of zinc. after a short time on adding the sheet of aluminium. No gas bubbles evolve on adding the sheet of copper.

Conclusion:

Zinc and aluminium replace the hydrogen of diluted acid forming a salt of the acid and hydrogen gas evolves because zinc and aluminium precede hydrogen in C.A.S. Copper doesn’t replace the hydrogen of diluted acid because copper comes after hydrogen in C.A.S.

Zn + 2HCl ZnCl2 + H2

2Al + 6 HCl 2AlCl3 + 3 H2

Cu + HClNo reaction

You can detect the evolving of hydrogen gas as a result of the substitution of metals to the hydrogen of diluted acids by approaching a burning match to it, so it burns with a pop sound.

Although aluminium comes before zinc in C.A.S., aluminium delays after zinc in the reaction with diluted hydrochloric acid due to the presence of a layer of aluminium oxide (Al2O3) on aluminium surface, which takes time to separate from aluminium, that delays the starting of occurrence of the reaction.

Both aluminium and zinc react with diluted hydrochloric acid, while copper doesn’t react with the same acid because both aluminium and zinc come before hydrogen in the chemical activity series, so they replace the hydrogen of acid, while copper comes after hydrogen in the chemical activity series, so it can’t replace the hydrogen of acid.

Sodium reacts with dil. HCI, while copper does not react with the same acid because sodium can replace the hydrogen of diluted acid as it comes before hydrogen in the chemical activity series, while copper comes after the hydrogen. Some metals replace other metals (in their salt solutions) that follow them in the chemical activity series.

(Metal A) + (Metal B salt solution) Metal A salt solution + Metal B ↓

Substitution of magnesium to copper in copper sulphate solution

Procedures: Put a magnesium sheet in a test tube containing blue copper sulphate solution.

Observation: The blue colour of copper sulphate disappears and a red precipitate is formed.

Conclusion: Magnesium is more active than copper (as it comes before copper in the chemical activity series) so, it substitutes copper in copper sulphate solution forming magnesium sulphate (colourless) and copper precipitates (red ppt.)

Mg + CuSO4 MgSO4 + Cu

Magnesium can replace copper in its salt solutions, while the opposite doesn’t occur because magnesium precedes copper in C.A.S., so it replaces copper, but copper follows magnesium, so it cannot replace magnesium.

A red precipitate is formed when magnesium is added to copper sulphate solution because magnesium comes before copper in the chemical activity series, so it replaces copper in copper sulphate solution and copper precipitates as a red ppt.

The blue colour of copper sulphate disappears on putting a piece of zinc in it because zinc comes before copper in the chemical activity series, so it substitutes copper in copper sulphate solution forming colourless zinc sulphate.

Don’t keep silver nitrate solution in aluminium containers because aluminium precedes silver in C.A.S., so it replaces silver in silver nitrate solution which leads to eroding of aluminium containers. As the distance between metals increases in C.A.S., as the substitution becomes faster.

Application

Potassium (K) reacts instantly with water, while magnesium (Mg) reacts very slowly with cold water because the distance between K & H is greater than the distance between Mg & H in C.A.S (K is more active than Mg).

Double substitution reactions

Double substitution reactions are chemical reactions in which double substitution (exchange) occurs between the ions (radicals) of two different compounds to give two other new compounds.

Double substitution reactions

Double substitution reactions

Types of double substitution reactions
  1. The reaction between an acid and an alkali (neutralization reaction).
  2. Reaction between an acid and a salt.
  3. Reaction between two salt solutions
Reaction between an acid and an alkali (neutralization reaction)

A neutralization reaction is a reaction between an acid and alkali to form salt and water.

Acid + Alkali Salt + Water

Example: Reaction between hydrochloric acid and sodium hydroxide to form sodium chloride (salt) and water.

NaOH + HCl NaCl + H2O

On heating the (resultants) of the previous reaction, H₂O evaporates and NaCl (table salt) remains.

Reaction between an acid and a salt

Acids react with salts and the resultant depends on the type of both the acid and salt.

The reaction between diluted hydrochloric acid and sodium carbonate

Procedures:

  1. Put an amount of diluted hydrochloric acid in a flask.
  2. Put a little amount of sodium carbonate salt in a balloon.
  3. Insert the top of the balloon over the edge of the flask.
  4. Slowly turn over the balloon in a way that makes the amount of sodium carbonate fall into the flask.

Observation:

An effervescence happens inside the flask which makes the balloon is blown.

5. Carefully close the balloon and take it away of the flask.

6. Pass the gas formed inside the balloon into a clear limewater in a test tube for a short time.

Observation: The clear limewater becomes turbid.

Conclusion: Diluted hydrochloric acid reacts with sodium carbonate salt-forming sodium chloride, water, and carbon dioxide gas evolves which turbids the clear limewater.

Na2CO3 + 2HCl 2NaCl + H2O + CO2

Reaction between two salt solutions

The reaction between two salt solutions is accompanied by the formation of a precipitate (ppt.) (salt doesn’t dissolve in water].

Example:

The reaction between sodium chloride solution and silver nitrate solution: Sodium chloride solution reacts with silver nitrate solution to give sodium nitrate solution and a white precipitate of silver chloride.

NaCl + AgNO3 NaNO3 + AgCl ↓

A white precipitate is formed on adding silver nitrate solution to sodium chloride solution due to the formation of silver chloride salt which doesn’t dissolve in water.

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Simple and double substitution reactions, Reaction between an acid & a salt

Chemical activity series, Chemical properties of metals & nonmetals

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